This might not be word perfect, but I think I can remember what was said on my basic course.
Careless=
An attempt to go for the ball, did not mean to commit the foul, had eyes on the ball only, that sort of thing. They were only trying to go for the ball, not trying to get the players as well.
We were also told that after 3/4 (own tolerance level), they should be cautioned for persistently infringing the laws of the game. Obviously, after having been warned. A perfect example of this is Paul Scholes. A lot of his fouls (as long as not sliding) are careless, and I have been to matches before were the referee has warned him 4 times, and then cautioning him! This is also when a referee cautions someone, and points to 3/4 points on the pitch, and shows a number of fingers (e.g. 3 fingers), to show that they have committed 3 fouls, and that is why they are being cautioned.
Reckless=
An attempt for the ball, but doesn't consider the safety of the opponent, e.g. sliding tackle. It includes un natural movements to commit the foul, e.g. stretching the leg out to trip the opposition. Also, 'tactical fouls', e.g. tripping an opponent to stop a counter attack.
Excessive force=
Does not consider the safety of the player, does not need to use that force, had no consideration for the player, and placed the opposition player in danger. This also includes how much control they have of themselves, e.g. 2 footed tackle.
I could've wrote longer explanations, but I could go on forever! And some may sound similar, but they are quite hard to distinguish in words, easier to show on a video!